Pressure is an important thermodynamic property because it affects the propellant’s burning rate, and also because it directly produces force. Pressure, however, is dependent on other thermodynamic properties such as temperature, and density. These properties are inter-related; and the inter-relatedness may be expressed through an equation of state, and the energy equation. In addition, another important process, heat transfer, must be accounted for. Propellant burning rapidly increases the internal pressure to a high level not only by producing low density gases, but also by releasing heat from the chemical reactions. However, the heat released is quickly transferred to the surrounding; and the pressure quickly decreases. A good heat transfer model along with a good set of data on the combustion product gases is essential for accurate estimation of CAD/PAD and ECS performances. The figures below illustrate the significance of heat-loss in a pyrotechnic event. The plots compare the actual performance data of a relatively large pyrotechnic retractor and the calculated results with assuming no heat-loss, i.e. an adiabatic process. It is seen that the adiabatic assumption noticeably over-predicts both the pressure output as well as the velocity: the total energy output is over-predicted by 47 percent. The solid blue curves represent the actual test data while the dashed blue curves represent the adiabatic calculation results. 
Pressure and Velocity Results of a Relatively Large Pyrotechnic Retractor An Illustration of the Significance of Heat Loss |